煅烧温度对Al-In-TiO2光催化纳米材料性能的影响Effects of calcination temperature on properties of Al-In-TiO2 photocatalytic nano-material
张文杰,都玲,陈金垒
摘要(Abstract):
采用溶胶-凝胶法制备0.5%Al-3%In-TiO2光催化剂,研究煅烧温度对材料性质和光催化降解活性的影响。结果表明,不同煅烧温度制备的0.5%Al-3%In-TiO2样品均为锐钛矿型TiO2晶型,TiO2晶粒尺寸和晶胞体积随煅烧温度升高增大。煅烧温度升高导致样品平均孔径增大,累积孔容积和比表面积减少。400℃制备的样品比表面积为108.9 m2/g,平均孔径为8.0 nm,累积孔容积为0.1395 cm3/g。0.5%Al-3%In-TiO2材料吸附染料能力随煅烧温度升高而下降。400℃制备的样品具有相对较强的光催化降解活性,经30 min光照后甲基橙溶液的降解率为58.1%。
关键词(KeyWords): TiO2;光催化;溶胶-凝胶;煅烧
基金项目(Foundation): 国家自然科学基金(41271251);; 沈阳理工大学辽宁省废水治理技术重点实验室开放基金(4771004kfs02)
作者(Author): 张文杰,都玲,陈金垒
DOI: 10.13289/j.issn.1009-6264.2014.11.001
参考文献(References):
- [1]Palacio M,Villabrille P I,Romanelli G P,et al.Preparation,characterization and use of V2O5-TiO2mixed xerogels as catalysts for sustainable oxidation with hydrogen peroxide of 2,3,6-trimethylphenol[J].Applied Catalysis A,2012,417-418:273-280.
- [2]Wang P H,Yap P S,Lim T T.C-N-S tridoped TiO2for photocatalytic degradation of tetracycline under visible-light irradiation[J].Applied Catalysis A,2011,399(1-2):252-261.
- [3]An T C,Liu J K,Li G Y,et al.Structural and photocatalytic degradation characteristics of hydrothermally treat mesoporous TiO2[J].Applied Catalysis A,2008,350(2):237-243.
- [4]张文杰,辛宏亮,李汝愿,等.煅烧时间对TiO2-Al2O3复合光催化材料性能的影响[J].材料热处理学报,2013,34(4):7-11.ZHANG Wen-jie,XIN Hong-liang,LI Ru-yuan,et al.Effects of calcination time on properties of TiO2-Al2O3composite materials[J].Transactions of Materials and Heat Treatment,2013,34(4):7-11.
- [5]曲晓光,宋云婷,刘青,等.Cr掺杂纳米TiO2的制备及其可见光催化性能[J].材料研究学报,2010,24(2):144-148.QU Xiao-guang,SONG Yun-ting,LIU Qing,et al.Preparation of nanocrystalline Cr-doped TiO2powders and their photocatalytic properties under visible light irradiation[J].Chinese Journal of Materials Research,2010,24(2):144-148.
- [6]López S M,Hidalgo M C,Navío J A.Synthesis,characterization and photocatalytic activity of Bi-doped TiO2photocatalysts under simulated solar irradiation[J].Applied Catalysis A,2011,404(1-2):59-67.
- [7]Araa J,Díaz O G,Miranda M.Acid photocatalytic degradation using Fe-TiO2catalysts:dependence of the degradation mechanism on the Fe catalysts content[J].Applied Catalysis B,2002,36(2):113-124.
- [8]Wang E J,Yang W S,Cao Y A.Unique surface chemical species on indium doped TiO2and their effect on the visible light photocatalytic activity[J].Journal of Physical Chemistry C,2009,113(49):20912-20917.
- [9]Gonzalez V R,Rodriguez A M,May M.Slurry photodegradation of 2,4-dich-lorophenxyacetic acid:A comparative study of impregnated and sol-gel In2O3-TiO2mixed oxide catalysts[J].Journal of Photochemistry and Photobiology A,2008,193(1):266-272.
- [10]Liu J W,Han R,Wang H T,et al.Degradation of PCP-Na with La-B co-doped TiO2series synthesized by the sol-gel hydrothermal method under visible and solar light irradiation[J].Journal of Molecular Catalysis A,2011,344(1-2):145-152.
- [11]Jaiswal R,Patel N,Kothari D C,et al.Improved visible light photocatalytic activity of TiO2co-doped with vanadium and nitrogen[J].Applied Catalysis B,2012,126:47-54.
- [12]Lee B Y,Park S H,Kang M,et al.Preparation of Al/TiO2nanometer photo-catalyst film and the effect of H2O addition on photo-catalytic performance for benzene removal[J].Applied Catalysis A,2003,253(2):371-380.
- [13]Liu S Y,Liu G C,Feng Q G.Al-doped TiO2mesoporous materials:synthesis and photodegradation properties[J].Journal of Porous Material,2010,17(2):197-206.
- [14]张文杰,陈金垒,王宏,等.煅烧温度对In-TiO2纳米材料光催化性能的影响[J].材料研究学报,2012,26(6):561-566.ZHANG Wen-jie,CHEN Jin-lei,WANG Hong,et al.Effects of calcination temperature on the photocatalytic activity of In-TiO2nano-material[J].Chinese Journal of Materials Research,2012,26(6):561-566.
- [15]张文杰,杨波.B掺杂TiO2光催化剂的制备和光催化性能[J].材料研究学报,2012,26(2):149-154.ZHANG Wen-jie,YANG Bo.Synthesis and photocatalytic properties of B-doped TiO2[J].Chinese Journal of Materials Research,2012,26(2):149-154.
- [16]Li F T,Zhao Y,Hao Y J,et al.N-doped P25 TiO2-amorphous Al2O3composites:One-step solution combustion preparation and enhanced visible-light photocatalytic activity[J].Journal of Hazardous Materials,2012,239-240:118-127.
- [17]Huo Y,Zhu J,Li J X.An active La/TiO2photocatalyst prepared by ultrasonication-assisted sol-gel method followed by treatment under supercritical conditions[J].Journal of Molecular Catalysis A,2007,278(1-2):237-243.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||